DONOR ACCEPTOR REACTIONS OF TITANIUM TETRACHLORIDE WITH FORMAMIDE AND N,N-DIMETHYL FORMAMIDE
نویسندگان
چکیده
منابع مشابه
N-(4-Methylphenyl)formamide
In the title compound, C(8)H(9)NO, the amide group makes a dihedral of 32.35 (1)° with the benzene ring. In the crystal, pairs of strong N-H⋯O hydrogen bonds link the mol-ecules into inversion dimers. Weak C-H⋯O inter-actions further connect the mol-ecules into chains along the a axis.
متن کاملN-(2-Ethoxyphenyl)formamide
The title compound, C(9)H(11)NO(2), was obtained as an unexpected product in an attempt to synthesize a triazene ligand. The title mol-ecule is almost planar, with the formamide and eth-oxy groups oriented at 2.7 (3) and 12.9 (2)°, respectively, with respect to the mean plane of the benzene ring. In the crystal, mol-ecules are linked by inter-molecular N-H⋯O hydrogen bonds, forming a chain alon...
متن کاملN-(2-Formamidoethyl)formamide
The complete molecule of the title compound, C(4)H(8)N(2)O(2), is generated by a crystallographic inversion center. The occurence of N-H⋯O hydrogen bonds results in the formation of a two-dimensional infinite network parallel to the (010) plane. In this plane, the hydrogen bonds define graph-set motif R(4) (4)(22) in a centrosymmetric array by the association of four mol-ecules.
متن کاملN-(4-Nitrophenethyl)formamide
The title compound, C(9)H(10)N(2)O(3), was synthesized by direct N-formyl-ation of 4-nitro-phenethyl-amine hydro-chloride with formic acid and sodium formate in the absence of catalyst and solvent. In the crystal structure, mol-ecules are linked by inter-molecular N-H⋯O hydrogen-bond inter-actions into chains parallel to the a axis.
متن کاملN-(2,4,6-Trimethylphenyl)formamide
The title compound, C(10)H(13)NO, was obtained as the unexpected, almost exclusive, product in the attempted synthesis of a manganese(I)-N-heterocyclic carbene (NHC) complex. The dihedral angle between the planes of the formamide moiety and the aryl ring is 68.06 (10)°. In the crystal, mol-ecules are linked by N-H⋯O hydrogen bonds, forming infinite chains along the c axis.
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ژورنال
عنوان ژورنال: Canadian Journal of Chemistry
سال: 1958
ISSN: 0008-4042,1480-3291
DOI: 10.1139/v58-216